GLOSSARY
QUICK FINDER
(Click on the first Letter of the Word)
Alkaline --
The patented advanced DI (drawing and ironing) technology
allows the metal can to be 30% thinner and 10% less in
weight than conventional cans.
Ampere-Hour
-- One ampere-hour is equal to a current of one
ampere flowing for one hour. A unit-quantity of electricity
used as a measure of the amount of electrical charge that
may be obtained from a storage battery before it requires
recharging. Ampere-Hour Capacity
-- The number of ampere-hours which can be delivered by a
storage battery on a single discharge. The ampere hour
ampere-hour capacity of a battery on discharge is determined
by a number of factors, of which the following are the most
important: final limiting voltage; quantity of electrolyte;
discharge rate; density of electrolyte; design of
separators; temperature, age, and life history of the
battery; and number, design, and dimensions of electrodes.
Anode -- In a primary
or secondary cell, the metal electrode that gives up
electrons to the load circuit and dissolves into the
electrolyte. The negative electrode during discharge, where
oxidation occurs. Conductive additives like carbon black and
binders are typically added to the redox active material in
forming the electrodes.
Aqueous Batteries --
Batteries with water-based electrolytes.
Available Capacity -- The
total battery capacity, usually expressed in ampere-hours or
milliampere-hours that are available to perform work. This
depends on factors such as the endpoint voltage, quantity
and density of electrolyte, temperature, discharge rate,
age, and the life history of the battery.
Battery -- A device
that transforms chemical energy into electric energy. The
term is usually applied to a group of two or more electric
cells connected together electrically. In common usage, the
term "battery" is also applied to a single cell, such as a
household battery.
Battery Types -- There
are, in general, two type of batteries: primary batteries,
and secondary storage or accumulator batteries. Primary
types, although sometimes consisting of the same active
materials as secondary types, are constructed so that only
one continuous or intermittent discharge can be obtained.
Secondary types are constructed so that they may be
recharged, following a partial or complete discharge, by the
flow of direct current through them in a direction opposite
to the current flow on discharge. By recharging after
discharge, a higher state of oxidation is created at the
positive plate or electrode and a lower state at the
negative plate, returning the plates to approximately their
original charged condition. (More on specific battery types)
Battery Capacity -- The
electric output of a cell or battery on a service test
delivered before the cell reaches a specified final
electrical condition and may be expressed in ampere- hours,
watt-hours, or similar units. The capacity in watt-hours is
equal to the capacity in ampere-hours multiplied by the
battery voltage.
Battery Charger -- A
device capable of supplying electrical energy to a battery
Battery-Charging Rate
-- The current expressed in amperes at which a storage
battery is charged.
Battery Voltage, final
-- The prescribed lower-limit voltage at which battery
discharge is considered complete. The cutoff or final
voltage is usually chosen so that the useful capacity of the
battery is realized. The cutoff voltage varies with the type
of battery, the rate of discharge, the temperature, and the
kind of service in which the battery is used. The term
"cutoff voltage" is applied more particularly to primary
batteries, and "final voltage" to storage batteries.
Synonym: Voltage, cutoff.
Ci -- The rated
capacity, in ampere-hours, for a specific, constant
discharge current (where i is the number of hours the cell
can deliver this current). For example, the C5 capacity is
the ampere-hours that can be delivered by a cell at constant
current in 5 hours. As a cell's capacity is not the same at
all rates, C5 is usually less than C20 for the same cell.
Capacity -- The
quantity of electricity delivered by a battery under
specified conditions, usually expressed in ampere-hours.
Carbon/Zinc
Cathode -- In a
primary or secondary cell, the electrode that, in effect,
oxidizes the anode or absorbs the electrons. The positive
electrode during discharge, where reduction occurs.
Cell -- An
electrochemical device, composed of positive and negative
plates, separator, and electrolyte, which is capable of
storing electrical energy. When encased in a container and
fitted with terminals, it is the basic "building block" of a
battery.
Charge -- Applied to a
storage battery, the conversion of electric energy into
chemical energy within the cell or battery. This restoration
of the active materials is accomplished by maintaining a
unidirectional current in the cell or battery in the
opposite direction to that during discharge; a cell or
battery which is said to be charged is understood to be
fully charged.
Charge Rate -- The
current applied to a secondary cell to restore its capacity.
This rate is commonly expressed as a multiple of the rated
capacity of the cell. For example, the C/10 charge rate of a
500 Ah cell is expressed as, C/10 rate = 500 Ah / 10 h = 50
A.
Charge, state of --
Condition of a cell in terms of the capacity remaining in
the cell. Voltage is supplied to the cell to store chemical
energy at the electrodes.
Charging -- The process
of supplying electrical energy for conversion to stored
chemical energy.
Constant-Current Charge
-- A charging process in which the current of a storage
battery is maintained at a constant value. For some types of
lead-acid batteries this may involve two rates called the
starting and finishing rates.
Constant-Voltage Charge
-- A charging process in which the voltage of a storage
battery at the terminals of the battery is held at a
constant value.
Cycle -- One sequence of
charge and discharge. Deep cycling requires that all the
energy to an end voltage established for each system be
drained from the cell or battery on each discharge. In
shallow cycling, the energy is partially drained on each
discharge; i.e., the energy may be any value up to 50%.
Cycle Life -- For
secondary rechargeable cells or batteries, the total number
of charge/discharge cycles the cell can sustain before it
becomes inoperative. In practice, end of life is usually
considered to be reached when the cell or battery delivers
approximately 80% of rated ampere-hour capacity.
Depth of Discharge --
The relative amount of energy withdrawn from a battery
relative to how much could be withdrawn if the battery were
discharged until exhausted.
Discharge -- The
conversion of the chemical energy of the battery into
electric energy. The spontaneous cell reaction where energy
is released and can be used to supply power.
Discharge, deep --
Withdrawal of all electrical energy to the end-point voltage
before the cell or battery is recharged.
Discharge, high-rate --
Withdrawal of large currents for short intervals of time,
usually at a rate that would completely discharge a cell or
battery in less than one hour.
Discharge, low-rate --
Withdrawal of small currents for long periods of time,
usually longer than one hour.
Drain -- Withdrawal of
current from a cell.
Dry Cell -- A primary
cell in which the electrolyte is absorbed in a porous
medium, or is otherwise restrained from flowing. Common
practice limits the term "dry cell" to the Leclanché cell,
which is the common commercial type.
Electrochemical Couple
-- The system of active materials within a cell that
provides electrical energy storage through an
electrochemical reaction.
Electrode -- An
electrical conductor through which an electric current
enters or leaves a conducting medium, whether it be an
electrolytic solution, solid, molten mass, gas, or vacuum.
For electrolytic solutions, many solids, and molten masses,
an electrode is an electrical conductor at the surface of
which a change occurs from conduction by electrons to
conduction by ions. For gases and vacuum, the electrodes
merely serve to conduct electricity to and from the medium.
Electrolyte -- A
chemical compound which, when fused or dissolved in certain
solvents, usually water, will conduct an electric current.
All electrolytes in the fused state or in solution give rise
to ions which conduct the electric current.
Electropositivity -- The
degree to which an element in a galvanic cell will function
as the positive element of the cell. An element with a large
electropositivity will oxidize faster than an element with a
smaller electropositivity.
End-of-Discharge Voltage
-- The voltage of the battery at termination of a discharge.
Energy -- Output
capability; expressed as capacity times voltage, or
watt-hours.
Energy Density -- Ratio
of cell energy to weight or volume (watt-hours per pound, or
watt-hours per cubic inch).
Float Charging -- Method
of recharging in which a secondary cell is continuously
connected to a constant-voltage supply that maintains the
cell in fully charged condition.
Fuel Cells -- A battery
where reactants are supplied to the cell from an external
source. An example is the H2 / O2 fuel cell, in which these
gases react (in separate half-reactions at separate
electrodes) to form protons and hydroxide, which are
combined to form water.
Galvanic Cell -- A
combination of electrodes, separated by
electrolyte, that is capable of producing electrical energy
by
electrochemical action.
Gassing -- The evolution
of gas from one or both of the electrodes in a cell. Gassing
commonly results from self- discharge or from the
electrolysis of water in the electrolyte during charging.
Internal Resistance --
The resistance to the flow of an electric current within the
cell or battery.
Lead Acid (See Sealed
Lead Acid)
Lithium Batteries
Lithium Ion Batteries
Memory Effect -- A
phenomenon in which a cell, operated in successive cycles to
the same, but less than full, depth of discharge,
temporarily loses the remainder of its capacity at normal
voltage levels (usually applies only to Ni-Cd cells). A
battery thus afflicted may "lose" its memory effect (that
is, it might be "fixed") by discharging fully and recharging
several times consecutively.
Negative Terminal --
The terminal of a battery from which electrons flow in the
external circuit when the cell discharges.
Nickel Cadmium Batteries
(Ni-Cd, "Nicad")
Nickel Metal Hydride
(Ni-MH)
Nonaqueous Batteries --
Cells that do not contain water, such as those with molten
salts or organic electrolytes.
Ohm's Law -- The formula
that describes the amount of current flowing through a
circuit. Voltage = Current × Resistance.
Open Circuit --
Condition of a battery which is neither on charge nor on
discharge (i.e., disconnected from a circuit).
Open-Circuit Voltage
-- The difference in potential between the terminals of a
cell when the circuit is open (i.e., a no-load condition).
Oxidation -- A
chemical reaction that results in the release of electrons
by an electrode's active material.
Parallel Connection
-- The arrangement of cells in a battery made by connecting
all positive terminals together and all negative terminals
together, the voltage of the group being only that of one
cell and the current drain through the battery being divided
among the several cells. See Series Connection.
Polarity -- Refers to
the charges residing at the terminals of a battery.
Positive Terminal --
The terminal of a battery toward which electrons flow
through the external circuit when the cell discharges.
Primary Battery -- A
battery made up of primary cells. See Primary Cell.
Primary Cell -- A
cell designed to produce electric current through an
electrochemical reaction that is not efficiently reversible.
Hence the cell, when discharged, cannot be efficiently
recharged by an electric current. These cannot be recharged;
use once and discard. Note: When the available energy drops
to zero, the cell is usually discarded. Primary cells may be
further classified by the types of electrolyte used.
Rated Capacity -- The
number of ampere-hours a cell can deliver under specific
conditions (rate of discharge, end voltage, temperature);
usually the manufacturer's rating.
Rechargeable --
Capable of being recharged; refers to secondary cells or
batteries.
Recombination --
State in which the gasses normally formed within the battery
cell during its operation, are recombined to form water.
Reduction -- A
chemical process that results in the acceptance of electrons
by an electrode's active material.
Seal -- The
structural part of a galvanic cell that restricts the escape
of solvent or electrolyte from the cell and limits the
ingress of air into the cell (the air may dry out the
electrolyte or interfere with the chemical reactions).
Sealed Lead Acid
Secondary Battery --
A battery made up of secondary cells. See Storage Battery;
Storage Cell. Based on chemically reversible redox
reactions, can be recharged many times.
Self Discharge --
Discharge that takes place while the battery is in an
open-circuit condition.
Separator -- The
permeable membrane that allows the passage of ions, but
prevents electrical contact between the anode and the
cathode.
Series Connection --
The arrangement of cells in a battery configured by
connecting the positive terminal of each successive cell to
the negative terminal of the next adjacent cell so that
their voltages are cumulative. See Parallel Connection.
Shelf Life -- For a
dry cell, the period of time (measured from date of
manufacture), at a storage temperature of 21°C (69°F) after
which the cell retains a specified percentage (usually 90%)
of its original energy content.
Short-Circuit Current
-- That current delivered when a cell is
short-circuited (i.e., the positive and negative terminals
are directly connected with a low-resistance conductor).
Starting-Lighting-Ignition (SLI)
Battery -- A battery designed to start internal
combustion engines and to power the electrical systems in
automobiles when the engine is not running. SLI batteries
can be used in emergency lighting situations.
Stationary Battery --
A secondary battery designed for use in a fixed location.
Storage Battery -- An
assembly of identical cells in which the electrochemical
action is reversible so that the battery may be recharged by
passing a current through the cells in the opposite
direction to that of discharge. While many non-storage
batteries have a reversible process, only those that are
economically rechargeable are classified as storage
batteries. Synonym: Accumulator; Secondar Battery. See
Secondary Cell.
Storage Cell -- An
electrolytic cell for the generation of electric energy in
which the cell after being discharged may be restored to a
charged condition by an electric current flowing in a
direction opposite the flow of current when the cell
discharges. Synonym: Secondary Cell. See Storage Battery.
Taper Charge -- A
charge regime delivering moderately high-rate charging
current when the battery is at a low state of charge and
tapering the current to lower rates as the battery becomes
more fully charged.
Terminals -- The
parts of a battery to which the external electric circuit is
connected.
Thermal Runaway -- A
condition whereby a cell on charge or discharge will destroy
itself through internal heat generation caused by high
overcharge or high rate of discharge or other abusive
conditions.
Trickle Charging -- A
method of recharging in which a secondary cell is either
continuously or intermittently connected to a
constant-current supply that maintains the cell in fully
charged condition.
Vent -- A normally
sealed mechanism that allows for the controlled escape of
gases from within a cell.
Voltage, cutoff --
Voltage at the end of useful discharge. (See Voltage,
end-point.)
Voltage, end-point --
Cell voltage below which the connected equipment will not
operate or below which operation is not recommended.
Voltage, nominal --
Voltage of a fully charged cell when delivering rated
current.
Wet Cell -- A cell,
the electrolyte of which is in liquid form and free to flow
and move.
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